生长时间对掺镓的ZnO的结构和性能的影响.docVIP

PAGE PAGE III 生长时间对掺镓ZnO纳米棒的结构和性能的影响 摘 要 氧化锌由于具有较宽的禁带宽度、以及较大的激子束缚能等优点，而成为人们关注的焦点。但其p-ZnO的制备困难，同时为了提高ZnO基异质结的发光性能，本文进行了以下研究： 本次实验采用水热法在蓝宝石的p型氮化镓衬底上生长了一种ZnO纳米棒结构。设计了不同生长时间的实验来观察ZnO棒的生长过程。通过扫描电子显微镜、PL谱对生长的ZnO纳米棒进行观察并对表征的结果做出了相应的分析。通过对比不同生长时间下的实验样品形貌和它们相对应的pl谱，我们发现对于生长氧化锌纳米棒的最适时间应在7h左右。而我们在分析它们的pl谱时，发现氧化锌在可见光区的峰不是太明显，分析可能原因是氧化锌的发光机制在可见区其机理与紫外区不同，可见区主要是低能位错发光。 关键字：水浴法；氧化锌纳米棒；镓掺杂；生长时间； Effects of growth time on the structure and properties of ZnO nanorods doped gallium Abstract Zinc oxide due to its wide band gap, and large exciton bound energy and other advantages, and become the focus of peoples attention. But the p-type ZnO preparation is difficult, also in order to improve the luminescence properties of ZnO based heterojunction, this article has carried on the following research: This experiment by hydrothermal method on sapphire p-type gallium nitride substrate growth a ZnO nanorod structures. Design the experiments with different growth time to observe growth process of ZnO rods. By scanning electron microscopy, PL spectra on the growth of ZnO nanorods were observed and to characterize the results has made the corresponding analysis. Through comparison of different growth time of experimental sample topography and their corresponding to the PL spectra, we found that for the growth of ZnO nanorods optimum time should be in about 7h. And we in the spectral analysis of their PL found zinc oxide in visible light peak is not too obvious, analysis may be the reason The luminescence mechanism of Zinc Oxide in the visible region and the mechanism of ultraviolet, visible light emitting area is mainly low energy dislocation. Key words: water bath method, Zinc Oxide nanorods, gallium doping, growth time 目 录TOC \o 1-3 \h \u 摘要 I Abstract II 第一章 绪论 2 引言 2 1.1 纳米材料的几个效应 3 1.1.1 尺寸效应 3 1.1.2 表面与界面效应 3 1.1.3 量子尺寸效应 3 1.1.4 宏观量子隧道效应 3 1.2 纳米材料的应用 4 1.2.1 纳米材料在医学界的应用 4 1.2.2 纳米材料在化学界的应用 4 1.2.3