钙基固硫剂对水煤浆性能影响的研究.docVIP

文章编号：0258-8013 (2006) 21-0099-05 中图分类号：TQ536 文献标识码：A 学科分类号：480 60 钙基固硫剂对水煤浆性能影响的研究 刘建忠，冯云岗，张光学，周俊虎，程 军，李艳昌，岑可法(浙江大学能源清洁利用国家重点实验室，浙江大学热能工程研究所，浙江省 杭州市310027) Study on Effect of Calcium Base Sulfur-retention Agent on the Performanceof Coal Water Slurry LIU Jian-zhong, FENG Yun-gang, ZHANG Guang-xue, ZHOU Jun-hu, CHENG Jun, LI Yan-chang, CEN Ke-fa (State Key Laboratory of Clean Energy Utilization, Institute for Thermal Power Engineering, Zhejiang University ,Hangzhou 310027, Zhejiang Province, China) PEF PEF嗖淵删恤卿沁艸辦般鮒脚趣槪瞬曾 ABSTRACT： Dcsulphurizd coal water slurry is a new kind of clean coal water mixture, which shows some SO2 removal efficiency during combustion and gasification. Sulfur-retention agent has some effect to the performance of coal water slurry. The viscosity, stability and rheology have been studied through adding different calcium base sulfur-retention agent and different Ca/S molar ratio in Xinwcn coal water slurrj; Tlic results show that the sulfur-retention agent has little effect on rheology of CWS, which still presents pseudoplastic fluid. But the viscosity of CWS increases, while the stability decreases a little? The data also shows that inorganic calcium has little effect on the performance of CWS than organic calcium? The viscosity of CWS with organic calcium agent keeps 1000-1200 niPa s when Ca/S=2. Sulfur release of CWS adding CaCO3 reduces from 98% to 52% when Ca/S molar ratio is 2 and combustion temperature is 1000°C? KEY WORDS： thermal power engineering; coal water slurry; viscosity; stability; sulfur-retention agent 摘要：脱硫型水煤浆是一种新型的淸洁水煤浆，在燃烧和气 化过程中具有固硫作用，但固硫剂对水煤浆性能有一定影 响。文中针对新汶水煤浆，在添加不同钙基固硫剂、不同 Ca/S比时对水煤浆的粘度、稳泄性、流变性和硫析出特性等 进行了研究，结果表明固硫剂不会对水煤浆流变性木质产生 影响，水煤浆仍然呈现为假舉性流体，但其粘度会增加，稳 定性有所卜?降。无机钙对水煤浆性能影响要小于有机钙，在 Ca/S=2时，添加无机钙后水煤浆粘度为1000- 1200mPa s 添加CaCO3(Ca/S=2)的水煤浆在100CTC燃烧，硫的析出率 由98% F降到52%。 基金项目：国家重点基础研究发展规划项冃(2004CB217701)；浙 江省科技攻关计划项目(2004C36010) o Project Subsidized by the Special Funds for Major State Basic Research Projects of China(2004CB