苏州大学聚合物合成与改性作业答案.pdfVIP

Chapter 1 1、 What are molecular weight and polydispersity of polymers? The molecular weight of polymers is actually the average molecular weight of polymers, which is used to describe the size of polymers and is associated with the properties of polymers, like mechanical strength and viscosity. And there are usually three kinds of molecular weight of polymers according to different methods: number-average molecular weight, weight-average molecular weight, and viscosity-average molecular weight. 1/ 2 1 NxMx NxM x NxM x Mn Mw Mv Nx NxMx NxMx Polydispersity of polymers is the exact molecular weight distribution of polymers and lies in the statistical variations present in the polymerization w n processes. The ratio of the two average molecular weights M/ M is often useful as a measure of the polydispersity of polymers. 2、 Please list the repeating unit of the following polymers and monomers to synthesize them: PSt 、PMMA、PAA、PVA、PIP 、PTFE. PSt (polystyrene) PMMA (polymethylmethacryla te) PAA(polyacrylic acid) PVA (polyvinyl alcohol) (imaginary) PIP (polyisoprene) PTFE (polytetrafluroethyle ne) 3、