TiO2对甲基橙的光催化降解的研究.docVIP

PAGE PAGE 20 TiO2对甲基橙的光催化降解的研究 摘要：本文主要先是关于现在的对TiO2光催化降解甲基橙的研究进展和现状。进而仔细研究TiO2光催化降解甲基橙的降解机理和其实际运用意义。然后通过6组实验了解影响TiO2光催化降解的因素，并且通过对各种因素的实验来得到最佳的实验效果。如TiO2的最佳投加量是0.8g/l。PH值在3的时候甲基橙变红色，也是光催化降解效率最大的时候，但是我们综合考虑还是选择不调节PH,甲基橙溶液的PH值为5.17，其降解效果和PH=3时的降解效率相差不大。也研究得出双氧水的最佳掺和比例是1.5/100。同时探讨了光照强弱对实验的影响，光强越大，其降解效率就越高。还在上述确定的最优条件下，来外加电源电压进行光电流测试，得到的结果是光电流对该光催化反应的促进作用几乎可以忽略不计。然后进行研究甲基橙初始浓度的影响，在一定范围内随着初始浓度增加，降解效率降低。从而得到最优的降解配方，然后对甲基橙，罗丹明B，金橙2，亚甲基蓝这四种染料进行降解，发现这四种染料都在一定程度上降解，说明这个降解配方的通用性。 关键词：TiO2；甲基橙；降解机理；光催化降解；影响因素 Study on the degradation of methyl orange by TiO2 photocatalytic Abstract:In this paper, first research on the progress and present situation of photocatalytic degradation of methyl orange by TiO2. And then carefully study the degradation mechanism of TiO2 photocatalytic degradation of methyl orange and its practical significance.Then understand the influence factors of TiO2 photocatalytic degradation through 6 groups of experiments , and to get the best result through a variety of experimental factors.Such as the optimum dosage of TiO2 is 0.8g/l.The methyl orange become red at ph=3 when the photocatalytic degradation efficiency become to the largest , but we chose not to adjust the PH, because methyl orange solution pH is 5.17,and the degradation efficiency at that PH had little difference with the degradation efficiency at PH=3.Also studied the best optimum blending ratio of hydrogen peroxide is 1.5/100.At the same time to investigate the effects of light intensity,we can see the intensity get greater, the degradation efficiency is higher.The optimal conditions were determined, and carry on the light current test under applied voltage, the result is the promote the role of the light current to photocatalytic reaction is almost negligible.Then the influence of initial concentration of methyl orange, in a certain range with the increase of the initial concentration, the degradation efficiency decreased.so we get the optimal formula for degradation of methyl orange, the