第九届国际会议分会场icwmt9speaker juncheng li.pptxVIP

The 9th International Conference on Waste Management and TechnologySeparation of Perovskite Phase from CaO-TiO2-SiO2-Al2O3-MgO System by SupergravityJuncheng Li , Zhancheng Guo, Yao Liang, and Huijuan LiuState Key Laboratory of Advanced MetallurgyUniversity of Science and Technology Beijing2014.10.29-31 BeijingU S T BDispersed distribution of titanium componentAccumulating:70 million tonsIncreasing:3 million tons/ per yearResulting in :waste of titanium resources environmental pollutionVery fine grains(10μm) Charateristics of Ti-slagComplex interfacial combination11.Introduction/ Charateristics of Ti-slagOrder of crystallization during cooling: L → CaTiO3 (S) +L → CaSiO3 (S) +L → CaSiO3 (S) ~1450oC~1300oC~1250oC~1200oCDensity differences:Perovskite crystals =4.10 kg/m3, melt =3.10 kg/m3 Figure 1 Phase diagram of CaO-TiO2-SiO2 Super-gravity technology may be used to separate perovskite phase from CaO-TiO2-SiO2-Al2O3-MgO BF Slag containing TiO221.Introduction/ Principle for Super-gravity separationFigure 2 Flow diagram to effectively utilize the titanium bearing blast furnace slag1. Blast furnace; 2. Torpedo car; 3. Slag ladle; 4. Feeding systerm; 5. Heating systerm; 6. Bottom blowing systerm;7. Perovskite crystals; 8. Rotating drum; 9. Screw conveyor; 10. Tailings; 11.Bearing; 12.Coupling; 13. Motor31.Introduction/Technical route to handle the Ti-slagFigure 3 Centrifugal separation apparatus in the experimentsFigure 4 Schematic diagram of centrifugal separation apparatus1.Counterweight; 2. Centrifugal axis; 3. Base; 4. Graphite crucible; 5. Gangue melt; 6. Resistance coil; 7. Perovskite crystals after centrifugal enrichment ; 8. Perovskite crystals before centrifugal enrichment; 9. Thermocouple; 10. Horizontal rotor; 11. Conductive slipping; 12. Temperature controller42.Experiment/ Centrifugal separation apparatus The chemical agent powder was melted at 1500℃ for 30 min → rapidly cooled to 1320 ℃ → at a cooling rate of 0.5 ℃/min for 60min → water quenched.Pre-