第4章化学反应速率和化学平衡.docxVIP

D 4Al D 4Al 2O3 (s) + 9Fe(s)==== 8Al(s) + 3Fe 3O4 (s) 第4章化学反应速率和化学平衡 1 .计算下列反应的 ArHm , A-Sm ° N2(g) + O2 (g) ==== 2NO(g) CaO(s) + H 2O(l) ==== Ca(OH) 2 (s) Pt 4NH3(g) + 5O2 (g) ==== 4NO(g) + 6H 2O(l) Fe2O3 (s) + 3CO(g) ==== 2Fe(s) + 3CO 2 (g) ? V2O5 2SO2 (g) + O2 (g) ==== 2SO 3 (g) 答：① N2(g) + O2 (g) ==== 2NO(g) ArHm =2 AfHm (NO, g) =2 90.25=180.5kJ/mol ArSm =2Sm (NO) - Sm (O2) - Sm (N2) =2 210.761-191.61-205.138=24.774J CaO(s) + H2O(l) ==== Ca(OH) 2 (s) ArHm = AfHm (Ca (OH) 2)-AfHm (H2O, l) -AfHm (CaO) = -986.09+285.830+635.09 =-65.17 kJ/mol ArSm = Sm (Ca (OH) 2) -Sm (H2O, l) -Sm (CaO) = 83.