电子自旋共振 经典讲座.ppt

Introduction to Electron Spin Resonance and Spin Trapping;Free Radicals and EPR;The EPR experiment;The EPR spectrometer;The EPR spectrum;The hyperfine effect;Hyperfine splitting of EPR spectra;8;Hyperfine splittings are additive;Direct EPR analysis of a radical;Direct EPR of a tyrosyl radical;Spin trapping: when direct EPR is not convenient or possible;Advantages of the nitrones;Nitrone spin traps;EPR spectra from DMPO adducts;EPR spectra from 4-POBN adducts;Nitroso spin traps;EPR spectra from methyl radical adducts of nitroso traps;DMPO-trapping the tyrosyl radical;Spin trap-derived hyperfine from MNP and MNP-d9;MNP-trapping the tyrosyl radical;Why not spin trap?;Why not spin trap?;Summary