固体表面吸附.pptVIP

② adsorption of multi - component A + S = AS bA, θA B + S = BS bB , θB 第二十页，共36页 （4）BET(Brunauer-Emmett-Teller) equation (1938) Basic assumption (a) Adsorption is multilayer (b) Surface is uniform and there is not interacting force among the molecules adsorbed. (c) adsorption heat above the first layer are the same and equal to the condensed heat of gas. 第二十一页，共36页 Vm: saturated amount of monolayer adsorption c : constant dependent on adsorption heat pv : saturated vapor pressure of adsorbat liquid at