英文文献汇报.ppt

硬膜板上催化作用下的自限性组装： 用在锂硫电池中的中尺度石墨烯纳米壳 汇报人：XXX 目录 精品资料 你怎么称呼老师？ 如果老师最后没有总结一节课的重点的难点，你是否会认为老师的教学方法需要改进？ 你所经历的课堂，是讲座式还是讨论式？ 教师的教鞭 “不怕太阳晒，也不怕那风雨狂，只怕先生骂我笨，没有学问无颜见爹娘 ……” “太阳当空照，花儿对我笑，小鸟说早早早……” Source of the article Research background A Li-S batteriy: high theoretical energy density of 2600 Wh/kg; S: naturally abundant, economically effective, and environmentally friendly; Graphene and other nanostructured carbon materials: excellent conductivity, high specific surface area, accommodate large volume expansion; Issues: Li-S battery: poor cycling life and rate performance S: large volumetric expansion，poor conductivity Graphene: couldn’t integrate all the structural benefits. The concept of HGNs might be a promising strategy, which yet calls for new synthetic methodology. Research background B 研究背景： 中空纳米结构对提升电池性能有巨大优势， 但传统方法难以制作 研究目的： 提升锂硫电池容量；提高电池稳定性 解决方案： 中空石墨烯纳米球壳结构，嵌入硫合成复合材料，作为电池正极 Abstract Hollow nanostructures： 表面积大；活性部位充分暴露；物质输运的动力学性能优良；表面通透性好 A mesoscale approach to fabricate graphene shells: 催化剂作用下，在原位形成的纳米颗粒上实现纳米石墨烯的自限性组装 Use: 石墨烯纳米球壳作为基体与S复合，用作锂硫电池正极材料 Properties: 初始放电容量：1520mAh/g(0.1C) 电流密度从0.1C提升至2.0C，70%容量保持 1000次循环，每次衰减0.06% Introduction Hollow nanostructures的优势 Applications： catalysis, adsorption, chemical sensors, drug/gene delivery, and energy storage/conversion systems Hollow nanocrystals： mesoscale hollow structure, nanoscale quantum effects, and atomic-scale periodic arrangement Hollow graphene nanoshells(HGNs)： favourable electrical conductivity, good surface functionality, mechanical/chemical stability, and biocompatibility Hollow nanostructures的合成困境 The template-free or self-templating bottom-up approaches：hardly extended to HGN synthesis； A template-involving top-down strategy：no catalytic capability to regularly manage the arrangement of carbon atoms； Thus, controllable synthesis of HGNs with an engineered hollow cavity, predetermined layer number, small size, and h