郭佩热电池用CoS的制备及其放电性能分析研究(最终).docxVIP

郭佩热电池用CoS的制备及其放电性能分析研究(最终) 郭佩热电池用CoS的制备及其放电性能分析研究(最终) 郭佩热电池用CoS的制备及其放电性能分析研究(最终) CoS2 的制备及其放电性能研究 吕坤 1,2，赵平 1,2，杨少华 1,2，高 虹 1,2 1.沈阳理工大学环境与化学工程学院，沈阳 110159； 2.辽宁省特种贮备电源工程技术研究中心，沈阳 110159） 纲要：为了制备出粒径小、放电性能高的热电池正极资料 CoS2，本文以 EDTA- 2Na为螯合剂，在不一样 pH 条件下，采纳水热法制备获得了不一样容貌的 CoS2，利 用 X射线衍射 (XRD 、扫描电子显微镜 (SEM、激光粒度散布仪对产物进行了 表征，最后将不一样容貌的 CoS2装置成单体电池进行放电测试。实验结果表示， 在酸性条件 pH=1，4）下制备的 CoS2呈空心球形，在中性条件 (pH=7下制备的 CoS2呈表面带有大批纳 M 级颗粒的块状，在碱性条件 (pH=9，11下制备的 CoS2 呈片状。随 pH的增大， CoS2资料的粒度渐渐减小，单体电池的放电平台电压逐 渐高升，内阻渐渐减小。 关 键 词： CoS2；容貌；粒度；热电池 中图分类号： TM911 文件表记码： A 文章编号： Preparation and Discharge Performance Study of CoS 2 Used forThermal Battery LV Kun 1,2, ZHAO Ping 1,2, YANG Shao-hua 1,2,GAO Hong 1,2 (1.School of Environmental Chemical Engineering, Shenyang Ligong University,Shenyang110159,China 。2. Special Reserve Battery Engineering Technology Research Center of Liaoning Province, Shenyang110159, China ） Abstract: In order to prepare the thermal battery cathode material CoS 2 with small particle size and high discharge performance,CoS 2 with different morphologies were synthesized by hydrothermal process under differentpH value conditions employing ethylenediaminetetraacetic acid disodium (EDTA-2Na as chelating agent. CoS 2were characterized by X-ray diffraction (XRD ,scanning electron microscopy (SEM and laser particle size analyzer.Finally, the CoS 2 of different morphologies were assembled into single cells for discharge test.The results show that the morphologies of the products could be tuned by the pH values of solutions. The CoS 2 materials with hollowsphere-like morphology are obtained in acid environment (pH =1, 4.The 1/11 blocksamples with many nanoparticles on the surfacecan be obtained in neutral environment (pH=7.The flake-like samplesareobtained inalkaline environment (pH =9,11. With the increase of pH values, the particle sizes of CoS 2 materials decrease gradually, the discharge platform voltages of single cells raise gradually and the resistances decrease gradually. Key wo