一步法合成磺酸型固体催化材料及其催化性能研究.docVIP

Abstract PAGE 9 PAGE 1 本科学生毕业论文 论文题目： 一步法合成磺酸型固体催化材料及其催化性能研究 学 院： 化学化工与材料学院 年 级： 专 业： 化学 姓 名： 学 号： 指导教师： 摘要 PAGE 30 PAGE I 摘要 科技的迅猛发展带动了我国的工业化进程，但是随着不可再生资源的急剧消耗和发展工业带来的严重环境污染，使人们寻找一种环境友好型的可再生能源的愿望日益迫切。生物柴油就是一种典型的环境友好的可再生能源。而固体酸催化剂的优良特性和对环境的友好行为成为当今生物柴油研究领域的热点。 本文设计了一种以葡萄糖、浓硫酸为原料，通过改变反应条件控制磺酸化和碳化，制备磺酸型固体酸催化剂。通过磺酸型固体酸催化剂催化甲醇与三丁酸甘油酯的酯交换反应，研究了醇油摩尔比、反应温度、反应时间等因素对反应的影响。用气相色谱法分析反应中甘油单酯 (MG)、甘油双酯(DG)、甘油三酯(TG)和脂肪酸甲酯(FAME)的含量。结果表明经催化剂用量为三丁酸甘油酯质量20 %，反应温度80 ℃ 关键词 固体酸催化剂；酯交换反应；生物柴油；磺化 Abstract Abstract PAGE III Abstract The rapid development of technology led to Chinas industrialization process, but with the serious environmental pollution brought about by the rapid consumption of non-renewable resources and industrial development, so that people looking for an environment-friendly renewable energy aspirations of increasingly urgent. Biodiesel is a typical environment-friendly renewable energy. The fine features of the solid acid catalyst and environmental friendly behavior become a hot area of ??research of todays bio-diesel. This paper designed glucose, concentrated sulfuric acid as raw materials, by changing the reaction conditions to control sulfuric acid and carbonation, the preparation of sulfuric acid type solid acid catalyst. Sulfuric acid type solid acid catalysts methanol and tributary ester exchange reaction of methanol to oil molar ratio, reaction temperature, reaction time and other factors on the reaction. Reaction ester of monoglyceride (MG), glycerol dieter (DG), triglyceride (TG) and fatty acid methyl esters (FAME) content by gas chromatography analysis. The results showed that the tributary quality by the amount of catalyst 20%, reaction temperature 80 ° C, reaction time 8 h, and the transesterification rate can reach about 95%. Key words Solid acid catalyst; transesterification; biodiesel; sulfonated PAGE 27 PAGE III 目录 TOC \o 1-3 \h \z \u 摘要 II Abstract III 第一章 前言 1 1.1 生物柴油概述正文采用宋体 1 1.1.1 生物柴油的定义 1 1.1.2