2013级定量分析课件纸板.pptx

; 历史表明，那些取得重大科学发现的科学家，他们对研究的目标有着深刻的认识，对工作有着极大的兴趣和热忱，对结果抱有极大的希望。 一个具有创新能力的人所应具备的重要品质就是兴趣和自信心，缺乏创造力主要是由于缺乏兴趣，兴趣是创新的推动力。 兴趣的产生首先依靠对科学的了解和认识。;Course Information ;Reference Books;Course Information and Requirements;Presentations;Challenges Solution;作业与课堂要求;Chapter 1  Introduction to Analytical Chemistry;The Definition of Analytical Chemistry;What Is Analytical Chemistry?;Terminology术语;A Typical Quantitative Analysis Procedure;Selecting an Analytical Method;Quantitative Analytical Chemistry;Introduction to Volumetric Titrimetry容量(滴定)分析法简介;Terminologies术语 for Volumetric Analysis容量分析;Classification of Volumetric Titrations by the Type of Reactions根据反应类型分类;Chemical Reactions Used for Titration（自学）;Classification of Titration Processes（自学）;基准物质(Primary Standard); Classification of Reagents 实验室常用试剂分类;标准溶液Standard Solution;Calculation for Standard Solution有关标准溶液的计算（自学）;Apparatus for Titrimetric Analysis 常用滴定分析仪器;Measuring Volume滴定分析中的体积测量;Calibration of Volumetric Glassware容量仪器校准方法;Questions about Measuring Volumefor You to Think about after Class;Some Important Units of Measurement;Quantities Units in Analytical Chemistry分析化学中常用的量 和单位;Example 1Describe the Preparation of 250.0 mL of 0.02000 mol·L-1 K2Cr2O7 from Solid K2Cr2O7 .配制0.02000 mol·L-1 K2Cr2O7标准溶液250.0mL,求m = ?;One Example: Generally titration is carried out at 0.02 mol·L-1. The appropriate manipulation is to make a 250 mL solution by weighing 1.47 g (±10%) K2Cr2O7 to 0.1 mg. 通常仅需要溶液浓度为0.02 mol·L-1左右, 做法是: 准确称量1.47g(±10%) K2Cr2O7基准物质, 于容量瓶中定容, 再计算出其准确浓度：;The number of Reaction Unit of A equals the number of Reaction Unit of B in one reaction. Precipitation沉淀 reaction: Charges电荷 Acid-base reaction: protons质子 Complexation络合reaction: coordination bonds 配位数 Redox氧化还原 reaction: electrons电子;Expressions to Understand about Reaction Unit Conservation Principle;Examples;Reaction Unit for MnO4-: Reaction Unit for Fe2+: Fe2+;One ExampleTo standardize concentration of 0.020mol·L-1Na2S2O3