物化上双语课件35-2.pptxVIP

版权所有：华东理工大学物理化学教研室;版权所有：华东理工大学物理化学教研室;Framework of the Chapter;;;Separation of the ponent system;Separation of the ponent system;3.1 Introduction;Various Expressions for the Compositions of ponent Systems ;Various Expressions for the Compositions of ponent Systems ;3.1 Introduction;Framework of the Chapter;版权所有：华东理工大学物理化学教研室;I. Thermodynamics of ponent Systems;1. Definitions and Physical Meanings;1. Definitions and Physical Meanings;Partial Molar Quantities;Partial Molar Quantities; ① Xi is the partial derivative of an extensive property X against ni ② Both X and nj are extensive properties, the ratio between them is irrelevant to the total amount of the system. ③ Xi is an intensive property determined by T, p and composition ;Difference between the Partial Molar Quantity Xi and the Molar Quantity;Physical Meaning of Partial Molar Quantity;Difference： Xi is the contribution of 1 mol of a substance i to a certain extensive property X of a homogeneous multi component system at a certain concentration. Xi* is the contribution to that of a system composed of a pure substance i.;2. Assembling Equation ;Example 1 ;Example 1 ;3. Gibbs-Duhem Equation;Significance of the Gibbs-Duhem Equation;Gibbs-Duhem Equation for Binaries;Example 2;Example 2;;5. Experimental Determination of Partial Molar Quantities ;5. Experimental Determination of Partial Molar Quantities ;I. Thermodynamics of ponent Systems;1. Homogeneous ponent Systems with Changeable Compositions;If the composition keeps unchanged, dni=0;;Fundamental Equations of Thermodynamics;Generalized Equations of State;Chemical Potential;Chemical Potential;2. Heterogeneous ponent Systems with Changeable Compositions ;;Fundamental Equations of Thermodynamics;I. Thermodynamics of ponent Systems