基础材料和有机材料 (12).pdfVIP

Chapter 3 The melt and glass Lecture 1 Melt structure 1. Description of melt structure: ‘polymer theory’ a. Silicate melt consists of siloxane polymers with different polymerization degrees: [Si O ]6-, 2 7 [Si O ]8-, ……[S O ](2n+2)-. 3 10 in 3n+1 b. Three-dimension fragments of SiO2 crystal also exist. c. The distribution of these polymers obeys geometric progression. 2. The formation of the polymers A. Analysi