基础材料和有机材料 (6).pdfVIP

2.4 Non-stoichiometric compounds Definition ：Non-stoichiometry means there is an excess or deficit of either cations or anions, the ratio of cations and anions is not integer or fixed. Non-stoichiometric compound is essentially the substitutional solid solution between the high and low valence ions for the same elements. Taking Fe0.95O for an example, the ratio of iron to oxygen is 0.95:1, it means a part of Fe2+ convert into Fe3+ . So Fe O can be