质量分析器及亚稳离子综述.pptxVIP

会计学 质量分析器 第1页/共35页◆质量分析器是质谱计的核心◆不同类型的质量分析器构成不同类型的质谱计 ◆不同类型的质谱计其功能，应用范围，原理， 实验方法均有所不同。 Mass Analysers:Factors to Consider第2页/共35页Upper mass limit:Highest m/z that can be detectedMay be offset by multiple chargesResolution:Distinct signals for similar m/z ratiosTransmission:Ratio of ions reaching detector: ions producedCostMass Analysers:Resolution (Resolving Power)第3页/共35页Ability to resolve two signals of similar m/zResolved if valley is 10%Higher resolution: greater accuracye.g. R=20,000: Separate m/z 100.0000 from m/z 100.0050Accuracy needed:High Resolution Mass Spectrometry (HRMS)Deter