从含氟废水中浓缩回收2,6-二氟苯甲酰胺.pdf

2019 • 17 基础研究 当代化工研究 21 Modern Chemical Research 从含氣废水中浓缩回收2, 6-二氟苯 甲酰胺 *张传亮 1李国才 I陈彦如彳常娜2 （1 •天津邦盛净化设备工程有限公司天津300221 2.天津工业大学天津300387） 摘要 ：2, 6-二氟苯甲酰胺是合成苯甲酰基腺类杀虫剂的重要中间体.随着全球苯甲酰基脉类农药的快速发展 ，2, 6-二氟苯甲酰胺的市场 需求增长迅速.而农药生产所产生的废水中含有大量的2, 6-二氟苯甲酰胺 ，传统工艺处理难度大 ，且无法实现回用 ，造成了资源的严重浪 费.本文介绍了一种利用膜法从含氟废水中回收提纯2, 6-二氟苯甲酰胺的新工艺 ，浓缩提纯废水中的2, 6-二氟苯甲酰胺 ，同时实现了无机 盐分的回收以及淡水的回用 ，具有较好餉工程应用前景. 关键词 ：含氟废水 ；电渗析 ；浓缩回收 ；反渗透 中图分类号 ：X703.1 文献标识码 ：A Recovery of 2, 6-Difluorobenzamide Concentrated from Fluorine Wastewater Zhang Chuanliang1, Li Guocai1, Chen Yanru2, Chang Na2 (1.Tianjin Banksheng Purizfzcation Equipment Engineering Co” Ltd., Tianjin, 300221 2.Tianjin Polytechnic University, Tianjin, 300387) Abstract: 2,6-Difluorobenzamide is an important intermediate in the synthesis of benzoylurea insecticides. With the rapid development of benzoylureapesticide, the market demand of 2, 6-Difluorobenzamide is increasing rapidly. However, the wastewaterproduced bypesticide production contains a large amount of 2, 6-Difluorobenzamide, which is difficult to be treated by traditional technology and cannot be reused, resulting in serious waste ofresources. Thispaper introduced a new technology ofrecovering andpurifying 2, 6-Difluorobenzamidefromfluorine wastewater by membrane method, concentrated 2,6-Difluorobenzamidefrom purifying wastewater, and also realized the recovery of inorganic salt and reuse offresh water Key words： fluoride wastewater； electrodialysisenrichment recyclings reverse osmosis 1引言 在传统工艺处理含氟废水的成本方面 ，全国每年有2000万 杀虫剂是农业生