预锂化技术及其在高比能硅负极中的应用_聂平.pdfVIP

6 5 Vol.6 No.5 2017 9 Energy Storage Science and Technology Sep. 2017   210016 doi: 10.12028/j.issn.2095-4239.2017.0088 O 646 A 2095-4239 201705-889-15 Prelithiation technologies and application in high energy silicon anodes NIE Ping , XU Guiyin, JIANG Jiangmin, WANG Jiang, FU Ruirui, FANG Shan, DOU Hui, ZHANG Xiaogang (College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, Jiangsu, China) Abstract: Nowadays, there is an ever-growing demand for lithium ion batteries (LIBs) with even higher energy densities, safety, and longer cycle life. Electrode materials, such as silicon, tin, and metal oxides, based on either conversion or alloying mechanism have attracted widespread attention for LIB anodes due to their high theoretical capacities. Unlike the conventional intercalation mechanisms, a large irreversible capacity loss (ICL) in the first cycle is one of the prime issues