北京化工大学中级化学配位立体化学.pptxVIP

北京化工大学中级化学配位立体化学第1页/共96页 ??第2页/共96页第3页/共96页1. Werner和配位化学的发展Alfred Werner (1866-1919) Received the Nobel Prize of Chemistry in 1913 for proposing the octahedral configuration of transition metal complexes. Werner developed the basis for modern coordination chemistry. 第4页/共96页第3页/共96页Originally, a complex implied a reversible association of molecules, atoms, or ions through weak chemical bonds. As applied to coordination chemistry, this meaning has evolved. Some metal complexes are formed virtually irreversibly and many are bound together by bonds that are quite strong.In modern coordination co