(7179)--水玻璃改性聚氨酯的制备及性能研究.pdfVIP

理论与研究 12 塑料科技PlasticsScienceandTechnology NO.05 2021 水玻璃改性聚氨酯的制备及性能研究 摘 要：制备了水玻璃改性的聚氨酯复合材料，并研究了水玻璃的加入量对聚氨酯复合材料的阻燃性能和力学 性能的影响。结果表明：水玻璃作为一种无机阻燃剂可以应用于聚氨酯的合成中，随着水玻璃掺入量的增加，聚氨 酯的阻燃性能不断提高，同时水玻璃也可以作为增强剂，改进聚氨酯复合材料的力学性能。SEM 分析表明，水玻璃 加入复合材料中，可以明显降低聚氨酯基体内部的微孔过大现象，从而使聚氨酯材料的力学性能得到改进。当水玻 璃用量为5 g 时，聚氨酯复合材料的拉伸强度和压缩强度达到最大值，分别为0.280 MPa 和0.068 MPa。 关键词：聚氨酯；水玻璃；阻燃性能；力学性能 中图分类号：TQ433.4 文献标识码：A 文章编号：1005-3360（2021 ）05-0012-04 DOI：10.15925/j.cnki.issn1005-3360.2021.05.003 PreparationandPropertiesofSodiumSilicateModifiedPolyurethane CUI Ya-ping, SHA Li-rong, CHEN Wen-long (Jilin Jianzhu University, Changchun 130118, China) ： Abstract The polyurethane composite material modified by water glass was prepared, and the influence of the addition amount of water glass on the flame retardant and mechanical properties of the polyurethane composite material was studied. The results show that water glass as an inorganic flame retardant can be used in the synthesis of polyurethane. With the increase in the amount of water glass, the flame retardant properties of polyurethane continue to improve. At the same time, water glass can also be used as a reinforcing agent to improve polyurethane composites. SEM analysis shows that the addition of water glass to the composite material can significantly reduce the phenomenon of excessive micropores in the polyurethane matrix, thereby improving the mechanical properties of the polyurethane material. When the amount of water glass is 5 g, the tensile strength and compressive strength of the polyurethane composite material reach the maximum, which are 0.280 MPa and 0.068 MPa, respectively. ： Keywords Polyurethane; Sodium silicate. Flame retardant property; Mechanical properties 聚氨酯是一种由NH—COOH 做主链的高分子聚合 聚氨酯中，提