阳离子介孔MnO2的制备及其对水中HPAM的吸附研究的中期报告.docxVIP

阳离子介孔MnO2的制备及其对水中HPAM的吸附研究的中期报告 摘要：本研究以Mn(NO3)2和CTAB为原料，在碱性条件下通过水热法制备了阳离子介孔MnO2。通过XRD、SEM、BET、FT-IR等手段对样品进行了表征。结果表明，制备得到的MnO2具有高度的结晶度和介孔结构，能够有效吸附水中的HPAM。进一步的吸附实验表明，在溶液pH为6、HPAM初始浓度为50mg/L、吸附时间为120min时，阳离子介孔MnO2对HPAM的吸附量最大为147.1mg/g。吸附动力学和等温吸附实验分析表明，HPAM在阳离子介孔MnO2上的吸附符合准二级动力学模型和Langmuir等温吸附模型，表明了吸附过程是化学吸附过程和单层分子吸附过程。 关键词：阳离子介孔MnO2；HPAM；吸附；准二级动力学模型；Langmuir等温吸附模型 Abstract: In this study, cationic mesoporous MnO2 was prepared by hydrothermal method using Mn(NO3)2 and CTAB as raw materials under alkaline conditions. The samples were characterized by XRD, SEM, BET, and FT-IR. The results showed that the prepared MnO2 had high crystallinity and mesoporous structure, which could effectively adsorb HPAM in water. Further adsorption experiments showed that under the conditions of pH 6, initial concentration of HPAM at 50 mg/L, and adsorption time of 120 min, the maximum adsorption capacity of cationic mesoporous MnO2 for HPAM was 147.1 mg/g. Adsorption kinetics and isotherm experiments showed that the adsorption of HPAM on cationic mesoporous MnO2 was in agreement with the pseudo-second-order kinetic model and Langmuir isotherm model, indicating that the adsorption process was a chemical adsorption process and a single-layer molecular adsorption process. Keywords: cationic mesoporous MnO2; HPAM; adsorption; pseudo-second-order kinetic model; Langmuir isotherm model.