均相反应动力学课件.pptxVIP

均相反应动力学  ;2.1 反应速率方程 2.1 The Rate Equation;The minus sign means disappearing;均相反应速率定义：单位时间内，单位体积反应混合物中某一组分i的反应量（或生成量）。;Caution 1 2;Caution 3;Caution 4;Caution 5;Based on unit mass of solid in fluid-solid systems;Based on unit volume of solid in gas-solid systems;In homogenous systems, the volume of fluid in the reactor is often identical to the volume of reactor. In such case V and VR are identical and Eqs2.1-7 and 2.1-11 are used interchangeable. In heterogeneous systems all above definitions of reaction rate encountered, the definition used in any particular situation often being a ma