基于聚降冰片烯给—受体双股电缆的构筑研究的中期报告.docxVIP

基于聚降冰片烯给—受体双股电缆的构筑研究的中期报告 摘要： 本研究旨在利用聚降冰片烯（PI）和受体分子构筑双股电缆，并探究其电化学特性及应用前景。本中期报告介绍了实验的具体过程及初步结果。首先，我们合成了两种含有电子受体基团的利福平和乙酰丙酮酰胺衍生物，并分别与PI进行反应得到 PI-LFP 和 PI-AcAc。接着，我们利用圆二色谱、核磁共振等技术对所得产物进行了表征，并通过红外光谱（IR）、紫外–可见光谱（UV-Vis）以及荧光光谱对其吸光度和荧光特性进行了研究。结果表明所得产物可以在溶液中形成双股电缆的结构，并具有良好的光电化学活性。 Abstract: This study aims to construct dual-strand cables using polyaniline (PI) and receptor molecules, and explore its electrochemical properties and potential applications. This interim report introduces the specific process of the experiment and the preliminary results. Firstly, we synthesized two derivatives containing electron acceptor groups, LFP and AcAc, respectively, which were respectively reacted with PI to obtain PI-LFP and PI-AcAc. Then, we characterized the obtained products by circular dichroism, nuclear magnetic resonance and other technologies, and studied their absorption and fluorescence properties through infrared spectroscopy (IR), ultraviolet-visible spectroscopy (UV-Vis) and fluorescence spectroscopy. The results show that the obtained products can form dual-strand cables in the solution and exhibit good photoelectrochemical activity.