多级孔道沸石材料的制备及催化反应研究的中期报告.docxVIP

多级孔道沸石材料的制备及催化反应研究的中期报告 摘要： 本文介绍了多级孔道沸石材料的制备及其用于催化反应的研究。首先，采用溶胶-凝胶法制备了NaY多级孔道沸石材料，并通过X射线衍射（XRD）、氮气吸附-脱附（BET）和透射电子显微镜（TEM）等手段对其微观结构进行了表征。结果表明，所制备的NaY沸石材料具有明显的多级孔道结构，其中主孔道大小为0.7 nm，次孔道大小为0.5 nm。 接着，将所制备的NaY沸石材料用于邻苯二甲酸二丁酯（DOP）的催化加氢反应。通过对不同反应条件下DOP的转化率和产物分布进行分析，发现NaY沸石催化剂的催化性能受到温度、氢气压力和反应时间等因素的影响。其中，在180 ℃和10 MPa的反应条件下，NaY沸石材料可以将DOP转化为丁醇和2-丁酸二丁酯等产物，且对DOP的转化率高达90%以上。 综上所述，本文提出了一种有效制备多级孔道沸石材料的方法，并明确了所制备的沸石材料在催化反应方面的潜在应用。该研究为沸石材料的制备及应用拓展提供了一定的参考。 关键词：孔道沸石材料，溶胶-凝胶法，邻苯二甲酸二丁酯，催化加氢反应 Abstract: This paper introduces the preparation of multi-channel zeolite material and its application in catalytic reaction. Firstly, NaY multi-channel zeolite material was prepared by sol-gel method, and its microstructure was characterized by X-ray diffraction (XRD), nitrogen adsorption-desorption (BET) and transmission electron microscope (TEM). The results show that the prepared NaY zeolite material has obvious multi-channel structure, with the main channel size of 0.7 nm and the secondary channel size of 0.5 nm. Next, the prepared NaY zeolite material was used in the catalytic hydrogenation reaction of di-n-butyl phthalate (DOP). By analyzing the conversion rate and product distribution of DOP under different reaction conditions, it was found that the catalytic performance of NaY zeolite catalyst was affected by factors such as temperature, hydrogen pressure and reaction time. Among them, under the reaction conditions of 180 ℃ and 10 MPa, NaY zeolite material can convert DOP into butanol and di-n-butyl phthalate, and the conversion rate of DOP is as high as 90% or more. In summary, this paper proposes an effective method for preparing multi-channel zeolite materials and clarifies the potential applications of the prepared zeolite materials in catalytic reactions. This study provides a reference for the preparation and application expansion of zeolite materials. Keywords: zeolite material, sol-gel method, di-n-butyl phthalate, catalytic hydrogenation reaction.