手性二胺金属钌配合物催化亚胺的不对称氢化反应研究的中期报告.docxVIP

手性二胺金属钌配合物催化亚胺的不对称氢化反应研究的中期报告 摘要： 本文主要介绍了手性二胺金属钌配合物的合成与性质，并探讨了其在不对称氢化反应中的应用。通过文献综述分析了当前不对称氢化反应研究的进展和存在的问题，并介绍了一些已有的催化剂。 接着，我们设计、合成了一种新型的手性二胺金属钌配合物，并对其进行了表征。初步的研究结果表明，该配合物在亚胺的不对称氢化反应中表现出一定的催化活性和选择性，但仍然需要进一步的优化。 进一步的研究将集中在寻找最优的催化剂反应条件，以及对反应机理进行更深入的研究。通过这些努力，我们希望能够为手性金属配合物在不对称氢化反应中的应用开辟新的研究方向。 关键词：手性二胺金属钌配合物；不对称氢化反应；催化活性；选择性；反应机理 Abstract: This paper mainly introduces the synthesis and properties of chiral diamine metal ruthenium complexes, and explores their application in asymmetric hydrogenation reactions. Through literature review, we analyzed the progress and problems in current research on asymmetric hydrogenation reactions, and introduced some existing catalysts. Next, we designed and synthesized a new type of chiral diamine metal ruthenium complex, and characterized it. The preliminary research results show that the complex exhibits certain catalytic activity and selectivity in the asymmetric hydrogenation reaction of imines, but further optimization is still needed. Further research will focus on finding the optimal reaction conditions of the catalyst, and studying the reaction mechanism in more depth. Through these efforts, we hope to open up new research directions for the application of chiral metal complexes in asymmetric hydrogenation reactions. Keywords: chiral diamine metal ruthenium complex; asymmetric hydrogenation reaction; catalytic activity; selectivity; reaction mechanism.