新型含二苯并硅杂环戊二烯单元聚合物的合成及其光物理性能研究的中期报告.docxVIP

新型含二苯并硅杂环戊二烯单元聚合物的合成及其光物理性能研究的中期报告 摘要 本报告描述了一种新型含二苯并硅杂环戊二烯单元聚合物的合成方法及其光物理性能的中期研究结果。该聚合物是通过催化剂转移聚合法在低温下合成的，经NMR、GPC等技术表征，聚合物的结构得到确认。该聚合物具有高热稳定性和良好的溶解性，可以从常用的溶剂中溶解，并且其溶液在紫外-可见光谱区域显示出强烈的吸收峰和荧光光谱峰，表明其具有良好的光物理性能。未来研究将集中于进一步探究该聚合物的电学性质和光学性质。 关键词：含二苯并硅杂环戊二烯单元；聚合物；光物理性能 Abstract This report describes a new method for synthesizing a polymer containing a dibenzosilole unit and its mid-term research results on photophysical properties. The polymer was synthesized by catalytic transfer polymerization at low temperature, and its structure was confirmed by NMR, GPC and other techniques. The polymer has high thermal stability and good solubility, can be dissolved in commonly used solvents, and its solution shows strong absorption and fluorescence peaks in the UV-visible spectral region, indicating good photophysical properties. Future research will focus on further exploring the electrical and optical properties of the polymer. Keywords: dibenzosilole unit; polymer; photophysical properties