四氯化钛以铜除钒及泥浆处理工艺探讨.docxVIP

本 科 毕 业 论 文 四氯化钛以铜除钒及泥浆处理工艺探讨 Discussion About the Removal of Vanadium from Titanium Tetrachloride by Copper Wire and the Treatment of Castoff Slurry 2.1.2 分离物组分物性特征 2.2 原料物系的分离方法 2.2.1粗TiCl4中主要杂质的精馏分离 2.2.2化学分离方法及氧化还原反应 3.1 国内外粗四氯化钛除钒工艺现状及水平 4.3 铜丝法除钒的热力学理论分析 4.3.1 电化学理论 4.3.2 铜丝法除钒的电化学计算 4.4 铜丝法除钒的不足及改进 四氯化钛以铜除钒及泥浆处理工艺探讨 专业班级：冶金0602 学生姓名：XXX 指导教师：XXX 职称： 副教授 四氯化钛是生产海绵钛和钛白的重要原料铜除钒、铝粉除钒、硫化氢除钒和有机物除钒法对粗TiCl4铜丝塔除钒废水沉淀泥浆处理工艺存在的问题提出一套治理方案，探讨沉淀泥浆经自氧化—铜钒分离—综合回收的处理新工艺，使沉淀泥浆中的铜和钒都得到了有效回收，并指出处理方案的特征是氢氧化钠溶液进行中和沉淀控制PH值达到11，温度在80℃搅拌反应1小时，铜浸出液的pH值控制在2.0—2.5，温度控制在80℃，钒的提取主要在温度为550℃焙烧下以V2O5的形式被回收，该工艺具有具有工艺简单、操作方便、金属回收率高、生产成本低、环境友好等优点。Discussion About the Removal of Vanadium From Titanium Tetrachloride by Copper Wire and the Treatment of Castoff Slurry Abstract Titanium tetrachloride is an important raw material of titanium sponge and titanium dioxide production .Vanadium impurities in crude TIC14 mainly are vanadium oxychloride and a small amount of vanadium tetrachloride , their presence make relative volatility(1.22)TIC14 and V0C13 are quite small , so in industrial production , generally remove vanadium by chemical method..Chemical method of removing vanadium in crude VOC13 im selective reduction or selective precipitation , and the insoluble vanadium compounds are mutual separated with In this paper, the physical characteristics components of liquid titanium tetrachloride is expatiated； compare and evaluate the strengths and weaknesses of four methods of industrial method to except vanadium and their applications； analyze and discuss the principle and the choice of separation methods of removal vanadium by copper wire； calculate the feasibility of redox reactions theoretically； analyse and research the waste generating from the technology of removal of vanadium by copper wire , and the important products in the process of recycling from wastes. In order to solve the problem of wastewater and castoff slurry in the process of removing