活性炭吸附处理锂电池厂含酯废水及微波再生实验.docxVIP

活性炭吸附处理锂电池厂含酯废水及微波再生实验 张志辉;郑天龙;王孝强;王指刚;马宇辉;汪群慧 【摘要】采用活性炭吸附的方法对锂电池产生的含酯废水进行预处理，研究了吸附 时间、初始pH值和活性炭投加量对废水COD去除的影响.吸附饱和后的活性炭用 微波进行再生，考察了辐照时间、微波功率及再生次数对活性炭再生效果的影响.结 果表明，当活性炭投加量为10g/L时吸附60min,含酯废水的COD去除率为 69.5%,可生化性从原水的0.05提高到0.25.当微波功率为420W、辐照时间为 6min时，活性炭可被有效地再生,再生效率高达98.0%,活性炭损失率约为5.2%.再 生前后活性炭的红外光谱图表明，活性炭表面官能团发生了变化，促进活性炭对污染 物质的吸附.％Lithium-ion batteries became an important direction for the clean energy development, but the ester-containing wastewater produced from the battery factory was not suitable for direct biological treatment,for its high levels of COD and low biodegradability.The treatment of ester- containing wastewater by activated carbon adsorption method was investigated in this study, especially the effects of adsorption time, pH conditions and activated carbon dosage on the COD removal rate. The saturated activated carbon was regeneratedby microwaveafter adsorption. The effects of irradiation time and microwave power on the activated carbon regeneration were also studied. Under the optimum conditions of activated carbon dosage was 10g/L, adsorption time of60min, the wastewater COD removal rate was 69.5%and biodegradability of raw water was improvedfrom 0.05 to 0.25. Moreover, under the conditions of the microwave power was 420 W and the irradiation time was 6min, the activated carbon could be effectively regenerated, the regeneration efficiency was 98.0%, and only about 5.2% was lost in the regeneration process.The infrared spectra of activated carbon before and after regeneration showed thatthe surface functional groups of the activated carbonhad changed,thus improved the adsorption of pollutants. 【期刊名称】《中国环境科学》 【年(卷)，期】2014(000)003 【总页数】6页(P644-649) 【关键词】锂电池;含酯废水;活性炭吸附;微波再生 【作者】张志辉;郑天龙;王孝强;王指刚;马宇辉;汪群慧 【作者单位】北京科技大学环境工程系，北京100083;北京科技大学环境工程系， 北京100083;华北电力大学可再生能源学院，北京102206;北京科技大学环境工 程系，北京100083;北京科技大学环境工程系，北京100083;北京科技大学环境 工程系，北京100083 【正文语种】中文 【中图分类】X703.5 作为一种清洁能源，锂电池的应用越来越普遍，但其生产过程所带来的环境污染问题 也日益引起人们的关注.目前，国内外对电池废水的处理主要集中在重金属的去除研 究上,对电池生产过程中产生的有机废水，尤其