ASTM D7134-05 美国材料与试验协会标准.pdfVIP

Designation:D7134−05(Reapproved2012)

StandardTestMethodfor

MolecularMassAveragesandMolecularMassDistribution

ofAtacticPolystyrenebyMatrixAssistedLaserDesorption/

Ionization(MALDI)-TimeofFlight(TOF)MassSpectrometry

(MS)1

ThisstandardisissuedunderthefixeddesignationD7134;thenumberimmediatelyfollowingthedesignationindicatestheyearof

originaladoptionor,inthecaseofrevision,theyearoflastrevision.Anumberinparenthesesindicatestheyearoflastreapproval.A

superscriptepsilon(´)indicatesaneditorialchangesincethelastrevisionorreapproval.

1.ScopeE691PracticeforConductinganInterlaboratoryStudyto

DeterminethePrecisionofaTestMethod

1.1Thistestmethodcoversthedeterminationofmolecular

mass(MM)averagesandthedistributionofmolecularmasses

forlinearatacticpolystyreneofnarrowmolecularmassdistri-3.Terminology

bution(MMD)ranginginmolecularmassesfrom2000g/mol3.1Definitions—Fordefinitionsoftechnicaltermspertain-

to35000g/molbymatrixassistedlaserdesorption/ionizationingtoplasticsusedinthistestmethodseeTerminologiesD883

time-of-flightmassspectrometry(MALDI-TOF-MS).ThistestandD1600.

methodisnotabsoluteandrequirestheuseofbiopolymersfor

thecalibrationofthemassaxis.Therelativecalibrationofthe

4.SummaryofTestMethod

intensityaxisisassumedtobeconstantforanarrowMMD.

Generally,thisisviewedascorrectifthe