径向流氦氢分离床穿透特性实验与模拟分析.pdfVIP

径向流氮氢分离床穿透特性实验与模拟分析

摘要：为系统深入研究径向流氨氢分离床的吸附穿透性能，指导结构设计，本研究借助COMSOL

Multiphysics软件耦合材料吸氢动力学方程、流体流动动量方程和质量传递方程，建立了径向床穿透数

学模型，并结合实验验证了模型的可靠性，利用模型对特性参数进行参数化扫描，分析其对穿透性能的

影响。结果表明，穿透实验结果与模拟数据符合较好，模型可靠。通过分析温度、高径比及孔隙率等参

数对床体穿透性能的影响，推荐氨氢分离床床体参数如下：床体吸附温度为室温～343K，在该温度范围

内升高温度对传质区长度及出口处浓度-时间曲线影响较小；随着高径比的增加，床体效率明显下降，其

床层的吸附效率、压阻效应及粉末的装填难度，粉末孔隙率推荐0.56～0.64。以上结果表明，本研究建

立的模型可较好地预测床体的吸附分离性能，可用于床体结构设计以及工艺参数的优化。

关键词：径向流；氮氢分离床；穿透特性；数值模拟

ExperimentalandSimulationAnalysisofBreakthroughCapacity

ofRadialFlowHelium-hydrogenSeparationBed

Abstract:Helium-hydrogenseparationbedisanimportantpartoftritiumextraction

system.Inordertodeeplystudypenetrationperformanceoftheradialflowbedand

guidethestructuredesign,themathematicalmodelofradialbedbreakthroughcapacity

wasestablishedbycouplingmaterialhydrogenabsorptionkineticsequation,masstrans-

ferequationandfluidflowmomentumequationinCOMSOLMultiphysics,whichwas

usedtocarryoutparametricscanningofthecharacteristicparameters,andtheeffectof

themodelonthebreakthroughcapacitywasanalyzed.Theresultsshowthatthebreak-

throughexperimentresultsareingoodagreementwiththesimulateddata,andthe

modelisreliable.Theeffectoftemperature,height-diameterratioandporosityonthe

breakthroughcapacitywasanalyzed.Theadsorptiontemperatureofthebedisfrom

roomtemperatureto343K.Inthistemperaturerange,increasingthetemperaturehas

lesseffectonthelengthofthemasstransferzoneandtheconcentration-timecurveat

182原子能科学技术第58卷

theoutlet.Withtheincreaseoftheheight-diameterratio,theefficiencyofthebed

decreasessignificantly,inwhichthehighefficiencyismaintainedforalongerperiodof

timewhenthehieght-diameterratiois2.00-8.33.Withtheincreaseofporosity,the

adsorptionefficiencyofthebeddecreasessignificantl