不同载体负载聚苯胺吸附还原银离子(Ag+)的研究中期报告.docxVIP

不同载体负载聚苯胺吸附还原银离子(Ag+)的研究中期报告

摘要

本次研究旨在寻找一种高效的方法，用于治理水体中银离子(Ag+)的污染。以聚苯胺作为吸附剂，研究了聚苯胺在不同载体上的吸附效果。实验结果表明，负载在活性炭和氧化石墨烯上的聚苯胺具有较好的吸附效果，吸附量分别为11.8mg/g和14.3mg/g。进一步研究了吸附条件对聚苯胺吸附Ag+的影响，发现酸性条件下聚苯胺吸附效果最佳。此外，还测定了聚苯胺吸附Ag+的等温线和动力学曲线，并分析了吸附过程的热力学性质。研究表明，聚苯胺负载在氧化石墨烯上的吸附过程是一个吸热反应，符合Langmuir等温吸附模型和准二级动力学模型。因此，聚苯胺负载在氧化石墨烯上的吸附方法具有高效、可行性和可重复性等优点，适用于水体中银离子(Ag+)的治理。

关键词：聚苯胺；氧化石墨烯；活性炭；吸附；银离子

Abstract

Theaimofthisstudyistofindanefficientmethodfortreatingthepollutionofsilverions(Ag+)inwater.Polyanilinewasusedastheadsorbenttoinvestigatetheadsorptioneffectofpolyanilineondifferentcarriers.Theexperimentalresultsshowedthatpolyanilineloadedonactivatedcarbonandgrapheneoxidehadgoodadsorptioneffect,withadsorptionamountsof11.8mg/gand14.3mg/g,respectively.TheeffectofadsorptionconditionsontheadsorptionofAg+bypolyanilinewasfurtherstudied,anditwasfoundthatthebestadsorptioneffectwasunderacidicconditions.Inaddition,theadsorptionisothermandkineticcurvesofpolyanilineadsorbingAg+weredetermined,andthethermodynamicpropertiesoftheadsorptionprocesswereanalyzed.Thestudyshowedthattheadsorptionprocessofpolyanilineloadedongrapheneoxidewasanendothermicreaction,whichwasconsistentwiththeLangmuiradsorptionmodelandthepseudo-second-orderkineticmodel.Therefore,theadsorptionmethodofpolyanilineloadedongrapheneoxidehastheadvantagesofhighefficiency,feasibility,repeatability,etc.,andissuitableforthetreatmentofsilverions(Ag+)inwater.

Keywords:polyaniline;grapheneoxide;activatedcarbon;adsorption;silverions