参考学习资料 化工 晶体的热学性质 声子 德拜模型 .pdf

ThermalhermalPPropertieropertiessooffSolidSolidss

Summary

L1

Densityofstates(1D)

g

2v

2

3V

gDensityofstates(3D)



23

2v

CC33RRDulongg–Petitlaw

2

kT

Einsteinmodel

CNke

kT



Debyemodel

2D4kT

3Ve

Cd

2322

2kT

vkT0e1

x3gk

Thermalexpansioncoefficient

T4a2

1

KCvThermalconductivity(non-metal)

3

22

1NkT



KFvFThermalconductivity(metal)

32E

F

1.5.1DensityofVibrationalStates

Atravellingwave,suchasthepropagationofasmallelasticdeformationina

solid,canberepresentedbyatrigonometriccosinefunction:

where22

uxtA,tkxcosk



Formathematicalconvenience,awavecanalsobeexpressed

incomplexexponentialform:itkxikx

uxtAe,Ae