液相色谱-串联质谱测定印染废水中3种碱性染料 .pdfVIP

液相色谱-串联质谱测定印染废水中3种碱性染料

马振英;郭浩

【摘要】Adeterminationmethodofbasicorange2,basicorange21and

basicorange22indyeingwastewaterbyliquidchromatography-tandem

massspectrometrywasdeveloped.Thebasicdyeswereextractedwitha

mixtureofethylacetateandcyclohexane(volumeratio1:1),andpurified

andconcentratedbygelpermeationchromatography,anddetectedby

liquidchromatographytandemmassspectrometry.Theresultsshowthat

thelinearrangesofthreebasicdyesarefrom5.0ng/mLto100.0ng/mL,

andR2isnolessthan0.9996,andthedetectionlimitsarefrom2.5μg/Lto

5.0μg/L,andtherecoveryratesarefrom88.6%to98.4%,andtherelative

standarddeviationsarefrom1.3%to2.7%.Themethodhashigh

automation,simplesamplepreparation,highsensitivity,lowdetectionlimit,

theaccurateandreliableresult,highrecoveryrateandgood

reproducibility,andcanbeusedfordeterminationofresiduesofbasic

dyesinprintinganddyeingwastewater.%建立了液相色谱-串联质谱法(LC-

MS/MS)测定印染废水中碱性橙2、碱性橙21、碱性橙22三种碱性染料的检测方

法.采用乙酸乙酯-环己烷混合溶液(体积比1:1)萃取碱性染料,经凝胶渗透色谱净化

浓缩,液相色谱-串联质谱仪测定,结果表明:3种碱性染料在5.0~100.0ng/mL范围

内,线性关系良好,相关系数(R2)大于0.9996;检出限在2.5~5.0μg/L之间;回收率在

88.6%~98.4%之间,相对标准偏差(RSD)在1.3%~2.7%之间.该方法自动化程度高、

样品前处理简单、灵敏度高、检出限低、结果准确可靠、回收率和重现性良好,可

用于印染废水中三种碱性染料残留量的同时测定.

【期刊名称】《当代化工》

【年(卷),期】2017(046)007

【总页数】4页(P1494-1497)

【关键词】液相色谱-串联质谱法;印染废水;碱性橙2;碱性橙21;碱性橙22

【作者】马振英;郭浩

【作者单位】枣庄市环境保护科学研究所有限公司,山东枣庄277100;枣庄市环境

监测站,山东枣庄277100

【正文语种】中文

【中图分类】TQ610.9;X703

Abstract:Adeterminationmethodofbasicorange2,basicorange21and

basicorange22indyeingwastewaterbyliquidchromatography-tandem

massspectrometrywasdeveloped.Thebasicdyeswereextractedwitha

mixtureofethylacetateandcyclohexane(volumeratio1:1),andpurified

andconcentratedbygelpermeationchromatography,anddetectedby

liquidchromatographytandemmassspectrometry.Theresultsshowthat

thelinearrangesof