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3.Abstract
Reactionsbetweenhexanuclearmanganesepivalatewithlanthanidesalts(chloridesornitrates),inthe
presenceofpotassiumhydroxide,2-pyridylmethanolandsodiumazideleadstoformationofanewfamily
ofhexaheteronuclearmanganese–lanthanideclusters.
4.Abstract
Twonovelmetal–organicframeworksof[M(ptz)(N)(HO)](M=Zn(1),Cd(2))(ptz=
323422
5-(4-pyridyl)tetrazolate)havebeenpreparedhydro(solvo)thermallybyreactionsof4-cyanopyridineand
excessNaNinthepresenceofzincandcadmiumchloride,respectively.Theoverallstructuremotifof
3
complexes1and2showpillaredlayeredframeworksandfeatureanunprecedented3-nodalnetwork
with(3,5,6)-connectivity.Thelayerisofparticularinterestasitisconstructedbyμ1,1–N3−andμ1,1,3–N3−
bridgingmodes,simultaneously.Furthermore,thesolidfluorescentpropertiesandTGAwerestudied.
5.Abstract
II
StructuralcharacterizationofanewselfassembledcoordinationpolymerofCu,hexamine(hmt)and
benzoate(OBz),[Cu(OBz)(hmt)](1),revealsthatitisacubicnon-interpenetratingdiamondoidnetwork
48n
formedbythecoordinationoftheμ-hmtligandtoalinear[Cu(OBz)]spacer.Themagneticstudy
424
revealsthattheCu(II)ionsareantiferromagneticallycoupled(J=−323.5cm−1)throughthesyn–syn
carboxylatebridges.
6.Abstract
2+
SimplePETchemosensorsbasedonanthraceneshowaselectiveturn-onfluorescencesensingforCu.
Theflexiblereceptorisfavorableforturn-on
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