ChemSusChem-2024-Patil-使用负载型铜催化剂强化糠醛合成环戊酮.pdfVIP

ResearchArticle

ChemSusChem/10.1002/cssc.202401484

IntensifyingCyclopentanoneSynthesisfromFurfuralUsing

SupportedCopperCatalysts

[a][a][a]

AdarshPatil,MaurikEngelbertvanBevervoorde,andFernandaNeirad’Angelo*

Thisworkaddressescatalyticstrategiestointensifythesyn-bedcancurbthislimitation.First,thefuranicringhydro-

thesisocyclopentanone,abio-basedplatformchemicalandagenationcanbesuppressedbyusingmilderconditions(i.e.,

potentialSAFprecursor,viaCu-catalyzedfurfuralhydrogenation°

150Cand7bar,and14secondsoresidencetime).Second,

inaqueousmedia.Whenperformedinasinglestep,usingFFAhydrogenationusingtandemcatalysis,i.e.,amixoβ-

eitheruniformorstagedcatalyticbedconfiguration,highzeoliteandCu/ZrO°

2,at180C,38barand0.6,allowssuicient

temperatureandhydrogenpressures(180°Cand38bar)aretimeforCPOformationandminimisespolymerisationoFFA,

necessaryformaximumCPOyields(37and49%,respectively).therebyresultingin60%CPOyield.Therefore,thiswork

Parallelfuranicringhydrogenationofurfuralandpolymer-recommendsasplitstrategytoproduceCPOfromfurfural.

isationointermediates,namelyfurfuryl