(2.4.2)--电离能和亲和能.pdfVIP

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2.4.2Theionizationenergyand

theaffinityenergy

I.Ionizationenergy:

Theminimumenergyrequiredtoremoveanelectron

fromoneofitsorbitals(inthegasphase).

A(g)A(g)e

Thefirstionizationenergy

I1E(A)E(A)

Thesecondionizationenergy

I2E(A2)E(A)

PeriodicTrendsinIonizationPotentials

II.Estimationofionizationenergy

+222221

Example:CC,1s2s2p1s2s2pZi

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