恒压变体积与定容间歇反应器作业及答案.pdfVIP

Homework2Assignment-CENG113-Spring2014

Problems1and2involveconstantpressure,variablevolumebatchreactors.

1)(2pts)2A→B,reactionis1st-orderinA,AandBaregases,k=6.0E-2s-1,T=300K,P=100kPa,

3

V=5.0E-3m.Findthevolumeand(X)atthefollowingreactiontimes:25,50,100s.ANSWER:

0A

333

2.1E-3m(0.777),2.6E-3m(0.95),2.5E-3m(1.0).

2)(2pts)A→3B,reactionis2nd-orderinA,AandBaregases,k=3.0E-3m3/mol/s,T=300K,P=

100kPa,V=3.0liters(L).Findthevolumeand(X)atthefollowingreactiontimes:25,50,75s.

0A

ANSWER:6.7L(0.62),7.5L(0.745),7.8E-3L(0.80).

Allproblemsbelowinvolveconstantvolumebatchreactors.

3

3)(2pts)A→Bisanenzyme-catalyzedreaction,r=-VC/(K+C),whereV=2.14E-3mol/m/s,

AMAMAM

33

KM=1mol/m,CA0=1mol/m.VMisnotthereactorvolumeV.UseaLevenspielplottoestimatethe

reactiontimeneededtoreach75%conversionofA.PlotpointsatXA=0.00,0.25,0.50and0.75.

Comparethistimeestimatetotheansweryouobtainbyintegratinganalytically.ANSWER:trxn=1000

sforanalyticalintegration-willdifferforLevenspielplot.

4)(2pts)Forthesamereactionasproblem3,useEulersmethodtoestimatetheconversionat600sby

takingstepsof200s.Comparethistimeestimatetoth