双联法制备100 kg级匀质TiNi合金铸锭.docxVIP

HotWorkingTechnology2020,Vol.49,No.7双联法制备

HotWorkingTechnology2020,Vol.49,No.7

双联法制备100kg级匀质TiNi合金铸锭

毛江虹\李炸飞；杨晓康I,王海1侯睿I

(1.西北有色金属研究院西安赛特思迈钛业有限公司，陕西西安710200;2.西安交通大学材料科学与工程学院，陕西西安710049)

摘要：目前国内工业生产的等原子比TiNi合金铸锭约20kg。为提高铸锭单重及其相转变温度的均匀性，采用真空感应熔炼(VIM)与真空自耗重熔(VAR)相结合的方法生产100kg级TiNi合金铸锭。对双联法制备^160mm-120kg的Ti-50.9Ni合金铸锭进行化学成分与相转变温度的检测。结果表明:Ti-50.9Ni合金降温时马氏体开始转变温度

-53°C,后续升温过程中奥氏体终了转变温度At=-18X2,属于低温TiNi二元合金。VIM+VAR二次铸锭的化学成分均匀，C、O元素含量降低。VIM+VAR二次铸锭中C含量显著降低，约为VIM一次铸锭的1/8,提高了相转变温度的均匀性，偏差达到±5°C的水平。分析不同熔炼方法对TiNi合金相转变温度均匀性的影响，总结出双联法的优势互补性。VIM制备的TiNi合金铸锭成分均匀,VAR进一步精炼、提纯、增大锭型，提出了制备大型匀质TiNi合金铸锭的新思路。

关键词：TiNi合金;VIM+VAR双联法；铸锭；相转变温度；均匀性

DOI:10.14158/j.cnki.1001-3814.中图分类号:TG243 文献标识码:A 文章编号:1001-3814(2020)07-0078-06

Preparationof100kgClassUniformTiNiAlloyIngotsbyDuplexProcess

MAOJianghong1,LIYefei2,YANGXiaokang1,WANGHai1,HOURui1

(1.XianSaiteSimaiTitaniumIndustryCo.,Ltd.,NorthwestInstituteforNonferrousMetalResearch,Xian710200,China;

2.SchoolofMaterialsScienceandEngineering,XianJiaotongUniversity,Xian710049,China)

Abstract:Atpresent,theweightofequalatomratioTiNialloyingotsareabout20kgproducedbydomesticindustry.Inordertoimprovethesingleweightoftheingotandtheuniformityofphasetransitiontemperature,100kgTiNialloyingotisproducedbythecombinationofvacuuminductionsmelting(VIM)andvacuumself-consumptionremelting(VAR).Thechemicalcompositionandphasetransitiontemperatureof(/160mm-120kgTi-50.9Nialloyingotpreparedbytheduplexprocessweredetected.TheresultsshowthatwhentheTi-50.9Nialloyiscooled,themartensitebeginstochangeatthetemperatureM=-53°C,duringthesubsequentwarmingprocess,theausteniteterminaltransitiontemperatureAfis

-18°C,andtheTi-50.9NialloybelongstothelowtemperatureTiNibinaryalloy.ThechemicalcompositionofVIM+VARsecondaryingotisuniform,theelementcontentso