Al掺杂调控SiGe合金的热电性能研究.docxVIP

第54卷第9期2025年5月

热加工工艺

HotWorkingTechnology

ISSN1001-3814CN61-1133/TG

DOI:10.14158/j.cnki.1001-3814.rjggy@

Al掺杂调控SiGe合金的热电性能研究程展旗1,李杰1,段兴凯2

(1.南昌大学物理与材料学院,江西南昌330031;2.九江学院九江市新能源材料及器件应用重点实验室,江西九江332005)

1摘要院SiGe合金是一种拥有巨大潜力的高温区热电材料遥在硅锗合金体系中袁p型SiGe合金系列热电材料的热电性能相对较低遥为了提升p型SiGe合金的热电性能袁最有效的手段是通过引入合适的第二相原子进行掺杂遥将Al掺杂到Si0.85Ge0.15当中袁采取电弧熔炼结合热压制备了Si0.85-xAlxGe0.15渊x=0袁0.015袁0.020袁0.025袁0.030冤块体样品袁探究了主元素掺杂对材料热电性能的影响遥结果表明袁Al部分替代Si后袁明显提高了载流子浓度袁改善了材料的热电性能遥其中样品Si0.85-xAlxGe0.15渊x=0.015冤在900K时袁功率因子提升至0.9伊10-3W窑m-窑K-2袁相比于没有掺杂的样品袁提高了约8倍遥合金样品的热电优值ZT值随着Al的掺杂也均有了一定提升袁并且在900K时袁Si0.85-xAlxGe0.15渊x=0.015冤的ZT值提升至最大袁为0.18遥

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关键词院SiGe合金曰掺杂曰载流子浓度曰功率因子曰热电性能

中图分类号院TB34 文献标识码院A 文章编号院1001-3814(2025)09-0087-05

ResearchonThermoelectricPropertiesofSiGeAlloyControlledbyAlDopingCHENGZhanqi1,LIJie1,DUANXingkai2

(1.SchoolofPhysicsandMaterials,NanchangUniversity,Nanchang330031,China;2.JiujiangKeyLaboratoryofNewEnergyMaterialsandApplicationDevices,JiujiangCollege,Jiujiang332005,China)

1Abstract院SiGealloyisakindofthermoelectricmaterialwithgreatpotentialinhightemperatureregion.Inthesilicongermaniumalloysystem,thethermoelectricpropertiesofp-typeSiGealloyseriesthermoelectricmaterialsarerelativelylow.Inordertoimprovethethermoelectricpropertiesofp-typeSiGealloys,themosteffectivemethodistointroduceappropriatesecond-phaseatomsfordoping.AlwasdopedintoSi0.85Ge0.15,andthebulksamplesSi0.85-xAlxGe0.15(x=0,0.015,0.020,0.025,0.030)werepreparedbyarcmeltingandhotpressing.Theeffectofmainelementdopingonthethermoelectricpropertiesofthematerialswasinvestigated.TheresultsshowthatthecarrierconcentrationissignificantlyincreasedandthethermoelectricpropertiesofthematerialareimprovedafterthepartialsubstitutionofAlforSi.ThepowerfactorofSi0.85-xAlxGe0.15(x=0.015)increasesto0.9伊10-3W窑m-窑K-2at