ZrO2增强Ti基复合材料的微观组织及耐腐蚀性能研究.docxVIP

2024年第53卷第23期Vol.53No.232024

热加工工艺

HotWorkingTechnology

ISSN1001-3814CN61-1133/TG

DOI:10.14158/j.cnki.1001-3814.rjggy@

ZrO2增强Ti基复合材料的微观组织及耐腐蚀性能研究

赵欢,刘靖宇

(太原理工大学机械与运载工程学院,山西太原030024)

摘要院采用放电等离子烧结的方式制备了不同氧化锆陶瓷掺杂量的钛基复合材料袁研究了氧化锆颗粒添加前后钛基复合材料的微观组织及物相组成曰测试并分析了氧化锆含量对钛基复合材料硬度和电化学腐蚀性能的影响规律遥结果表明院钛基复合材料主要由等轴状初生琢相尧茁相和次生琢相及弥散分布的氧化锆增强相组成曰随氧化锆陶瓷颗粒含量的增多袁钛基复合材料的硬度从纯钛的282.26HV显著提升至5wt%氧化锆含量对应的484.32HV袁且复合材料的腐蚀电位正移袁腐蚀电流密度降低袁复合材料的耐腐蚀性能提升遥5wt%氧化锆含量的钛基复合材料具有更加优异的力学性能和耐腐蚀性能遥

关键词院钛基复合材料曰氧化锆陶瓷增强相曰硬度曰耐腐蚀性

中图分类号院TB333.1+3 文献标识码院A 文章编号院1001-3814(2024)23-0147-05

StudyonMicrostructureandCorrosionResistanceofZrO2ReinforcedTiBasedCompositeMaterialsZHAOHuan,LIUJingyu

(CollegeofMechanicalandVehicleEngineering,TaiyuanUniversityofTechnology,Taiyuan030024,China)Abstract院TibasedcompositeswithdifferentdopingamountofZrO2ceramicswerepreparedusingsparkplasma

sintering,andthemicrostructureandphasecompositionoftheTibasedmaterialsbeforeandaftertheadditionofZrO2particleswerestudied,andtheinfluenceofZrO2contentonthehardnessandelectrochemicalcorrosionpropertyofTibasedcompositematerialswastestedandstudied.TheresultsindicatethattheTibasedcompositematerialsmainlyconsistofequiaxedprimary琢phase,茁phase,secondary琢phaseanddispersedZrO2reinforcementphase.WiththeincreaseofZrO2content,thehardnessofTibasedcompositematerialssignificantlyincreasesfrom282.26HVofpuretitaniumto484.32HVofthecompositewith5wt%ZrO2,andthecorrosionpotentialofthecompositematerialsshiftspositively,andthecorrosivecurrentdensitydecreases,andthecorrosionresistanceofthecompositematerialsimproves.TibasedcompositeswithZrO2contentof5wt%exhibitssuperiormechanicalpropertiesandcorrosionresistance.

Keywords院Tibasedcompositematerials;ZrO2ceramicreinforcementphase;hardness;corrosionresistance

钛合金具有比强度高尧耐腐蚀性能优异尧生物相容性好等优势而被广泛用于