英文版论文资料：Semi-quantitative analysis of the structural evolution of mesophase pitch-based carbon foams by Raman and FTIR spectroscopy.pdfVIP

第39卷第4期新型炭材料（中英文）Vol.39No.4

2024年8月NEWCARBONMATERIALSAug.2024

Citethis:NewCarbonMaterials,2024,39(4):668-680DOI:10.1016/S1872-5805(24)60867-X

Semi-quantitativeanalysisofthestructuralevolutionofmesophase

pitch-basedcarbonfoamsbyRamanandFTIRspectroscopy

LIUYue,CHANGSheng-kai,SUZhan-peng,HUANGZu-jian,QINJi,YANGJian-xiao*

（HunanProvinceKeyLaboratoryforAdvancedCarbonMaterialsandAppliedTechnology,CollegeofMaterialsScienceand

Engineering,HunanUniversity,Changsha,410082,China）

Abstract：Graphitizedcarbonfoams(GFms)werepreparedusingmesophasepitch(MP)asarawmaterialbyfoaming(450°C),

pre-oxidation(320°C),carbonization(1000°C)andgraphitization(2800°C).ThedifferencesinstructureandpropertiesofGFms

preparedfromdifferentMPprecursorspretreatedbyballmillingorliquidphaseextractionwereinvestigatedandcompared,and

semi-quantitativecalculationswereconductedontheRamanandFTIRspectraofsamplesateachpreparationstage.Semi-quantitat-

ivespectroscopicanalysisprovideddetailedinformationonthestructureandchemicalcompositionchangesoftheMPandGFmde-

rivedfromit.Combinedwithmicroscopicobservations,thechangefromprecursortoGFmwasanalyzed.Theresultsshowedthat

ballmillingconcentratedthedistributionofaromaticmoleculesinthepitch,whichcontributedtouniformfoamingtogiveaGFm

withauniformporedistributionandgoodpropertie