ZL303铝合金表面微弧氧化陶瓷膜的微结构和耐蚀性研究.docxVIP

HotWorkingTechnology2020,Vol.49,No.4

ZL303铝合金表面微弧氧化陶瓷膜的微结构和耐蚀性研究

陈建清1,赵新灿1,葛熔熔1,宋丹1,2,江静华1,马爱斌1,2,李程1,杨发林1(1.河海大学力学与材料学院,江苏南京210098;2.河海大学研究院,江苏宿迁223800)

摘要：为提高ZL303铝合金耐蚀性能，采用微弧氧化技术在ZL303铝合金表面制备陶瓷质氧化膜。通过扫描电镜观察了微弧氧化膜层表面及截面的微结构。利用X射线衍射仪分析了膜层的物相组成。采用腐蚀电化学和高温浸泡实验测试了微弧氧化膜层的耐蚀性。结果表明：所制备的膜层厚度约为13μm，主要由α-Al2O3和γ-Al2O3组成，外表面存在大量微米级等离子放电微孔。经微弧氧化处理后，试样的电化学阻抗半径增大，自腐蚀电位上升，腐蚀电流密度减

小。在高温腐蚀环境中，微弧氧化膜层能有效阻挡腐蚀介质对铝合金基体的侵蚀破坏，耐蚀性能得到提高。关键词：铝合金；微弧氧化；微结构；耐蚀性能

DOI:10.14158/j.cnki.1001-3814.中图分类号：TG174.451 文献标识码：A 文章编号：1001-3814(2020)4-0096-05

ResearchonMicrostructureandCorrosionResistanceofMicro-arcOxidatedCeramicCoatingonZL303AluminumAlloySurface

CHENJianqing1,ZHAOXincan1,GERongrong1,SONGDan1,2,JIANGJinghua1,

MAAibin1,2,LICheng1，YANGFalin1

(1.CollegeofMechanicsandMaterials,HohaiUniversity,Nanjing210098,China;2.GraduateSchoolofHohaiUniversity,Suqian223800,China)

Abstract：InordertoimprovethecorrosionresistanceofZL303aluminumalloy,theceramicoxidefilmswerepreparedonthesurfaceofZL303aluminumalloybymicro-arcoxidation(MAO)technology.Thesurfaceandcross-sectionalmicrostructureofthecoatingswereobservedbyscanningelectronmicroscopy.ThephasecompositionofthefilmwasanalyzedbyX-raydiffractometer.ThecorrosionresistanceofMAOcoatingswastestedbyelectrochemicalcorrosiontestsandhightemperatureimmersioncorrosiontest.Theresultsshowthatthepreparedcoatingthicknessisabout13μm,whichismainlycomposedofα-Al2O3andγ-Al2O3,andtheoutersurfacegeneratesalargenumberofmicronplasmadischargemicropores.AfterMAOtreatment,theelectrochemicalimpedanceradiusofthesampleincreasesandtheselfcorrosionpotentialelevatesobviously,andthenthecorrosioncurrentdensitydecreases.TheMAOcoatingcaneffectivelyblockthecorrosiondestructionofthealuminumalloymatrixbythecorrosivemediuminhighte