铜、铁和锆三种金属有机框架的微观结构与抗菌性能（英文）.docxVIP

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铜、铁和锆三种金属有机框架的微观结构与抗菌性能（英文）

一、IntroductiontoMetal-OrganicFrameworks(MOFs)

1.DefinitionandStructureofMOFs

Metal-OrganicFrameworks(MOFs)representaclassofporousmaterialsthatareconstructedfrommetalionsorclusterscoordinatedwithorganicligands.Thesematerialsarecharacterizedbytheirhighsurfaceareaandtunableporesize,whichmakethemsuitableforawiderangeofapplications.ThestructureofMOFsisdefinedbythearrangementofthemetalnodesandtheorganiclinkers.Themetalnodesaretypicallymetallicionsorclusters,whiletheorganiclinkersareorganicmoleculesorpolymersthatactasbridgesbetweenthemetalnodes.ThisuniquecombinationofmetallicandorganiccomponentsgivesMOFstheirdistinctiveproperties.

TheconstructionofMOFsinvolvestheself-assemblyofmetalnodesandorganicligandsinastepwiseprocess.ThemetalnodesserveastheprimaryframeworkoftheMOF,providingthebackbonestructure.Theorganicligandsthencoordinatewiththemetalnodestoformathree-dimensionalnetwork.Thisprocessisdrivenbytheinteractionsbetweenthemetalnodesandtheorganicligands,whichincludecoordinationbonds,vanderWaalsforces,andhydrogenbonds.TheresultingMOFstructureexhibitsahighlyorderedarrangementofthemetalnodesandorganicligands,leadingtowell-definedporesandchannelswithinthematerial.

TheporestructureofMOFsisacriticalfactorindeterminingtheirfunctionality.Thesize,shape,andconnectivityoftheporescanbetailoredduringthesynthesisprocesstosuitspecificapplications.Forexample,smallporesaresuitableforgasstorageandseparation,whilelargerporesmaybemoreeffectiveforcatalysisoradsorption.ThesurfaceareaofMOFsisalsoanimportantcharacteristic,asitinfluencesthematerialsadsorptioncapacityandcatalyticactivity.ThehighsurfaceareaofMOFsisattributedtothepresenceofnumeroussurface-activesite