微量In对Mg-4Sn合金微观组织、电化学行为和放电性能的影响.docxVIP

2024年第53卷第11期Vol.53No.112024

热加工工艺

HotWorkingTechnology

ISSN1001-3814CN61-1133/TG

DOI:10.14158/j.cnki.1001-3814.rjggy@

微量In对Mg-4Sn合金微观组织尧电化学行为和放电性能的影响

张研研1,张忠涛2,王勋1,李航1

(1.太原理工大学材料科学与工程学院,山西太原030024;2.金龙精密铜管集团股份有限公司,重庆404188)

摘要院向铸态Mg-4Sn合金中添加1.0wt%In袁研究了微量In对合金微观组织尧电化学行为和放电性能的影响遥结果表明袁添加In元素前后袁合金的微观组织均由树枝晶形态的琢-Mg基体以及在枝晶间弥散分布的Mg2Sn相组成遥添加In元素后袁In固溶于基体中袁且合金的树枝晶尺寸变小袁Mg2Sn相的均匀性提高曰合金的开路电位更负袁自腐蚀电流密度更低曰在电池性能的测试中袁合金表现出更平稳的放电过程尧更负的放电电位和更高的阳极效率遥这主要归因于加入In后合金更高的放电活性和更疏松的放电产物遥

关键词院镁空气电池曰Mg-Sn合金曰微观组织曰电化学性能曰放电性能

中图分类号院TG146.22 文献标识码院A 文章编号院1001-3814(2024)11-0078-04

EffectofTraceInonMicrostructure,ElectrochemicalBehaviorandDischargePerformanceofMg-4SnAlloy

ZHANGYanyan1,ZHANGZhongtao2,WANGXun1,LIHang1

(1.SchoolofMaterialsScienceandEngineering,TaiyuanUniversityofTechnology,Taiyuan030024,China;2.GoldenDragonPreciseCopperTubeGroupInc,Chongqing404188,China)

Abstract院1.0wt%InwasintroducedtoMg-4Sncastalloy,andtheeffectsoftraceInonitsmicrostructure,electrochemicalpropertyanddischargeperformancewerestudied.TheresultshowsthatthemicrostructureofthealloybeforeandafteraddingInelementconsistsofdendritic琢-MgmatrixandasmallamountofMg2Snphasescatteredalonggrainboundary.AftertheadditionofIn,itdissolvesintothematrix,andthedendriticcrystalsizedecreases,theuniformityofMg2Snphaseimproves,theopencircuitpotentialofthealloyismorenegative,theself-corrosioncurrentdensityislower.Inthebatteryperformancetesting,thealloywithadditionofInshowsasmootherdischargeprocess,morenegativedischargepotentialandbiggeranodeefficiency.ThisismainlyattributedtothehigherdischargeactivityandlooserdischargeproductsofthealloyaftertheadditionofIn.

Keywords院Mg-airbattery;Mg-Snalloy;microstructure;electrochemicalproperty;dischargeperformance

镁空气电池因高能量密度尧环保性和低成本成为绿色储能领域的代表[1-2]遥然而袁其商业化应用仍有几大障碍[3-4