有机化合物命名与异构体结构分析.pptxVIP

C6H14?hasfiveisomersAHexaneB??2-methylpentane????C??3-methylpentane????D??2,2-dimethylbutane????E??2,3-dimethylbutaneNamingOrganicCompoundsExamplesofsomecommon?alkylgroups

StructuralFormulasforC4H10OIsomersDifferentcompoundshavingthesamemolecularformulaarecalled?isomers,andtheprevalenceoforganicisomersreflectstheextraordinaryversatilityofcarboninformingstrongbondstoitselfandtootherelements.

(a)MOEnergy-Level

DiagramforH2Molecule,(b)ShapesofMOs

MOEnergy-LevelDiagramforHe2Molecule

MOEnergy-levelDiagramforB2Fillingmolecularorbitalss2sands2pworksthesameaswhenfillings1sorbitals.Filldegenerateorbitalsp2pseparately,thenpairwisewithelectronshavingoppositespins.MolecularorbitaldiagramshowsthatB2moleculeisparamagnetic.BOinB2=?(4–2)=1σ*2sσ2sEπ2pσ2pπ*2pσ*2p

Dyesensitizedsolarcells(Graetzelcells)DyemoleculesarehitbylightElectronsinthedyearetransmittedtoTiO2.Theelectronsarecollectedbyfrontelectrodeandsuppliedtoexternalload.Dyemoleculesareelectricallyreducedtotheirinitialstatesbyelectronstransferredfromredoxcoupleintheelectrolyte.Theoxidizedionsintheelectrolyte,diffusetothebackelectrodetoreceiveelectron