参比电极体系内阻对电化学阻抗谱的影响_1000003381119111.pdfVIP

第13卷第3期腐蚀科学与防护技术Vol13No3

2001年5月May2001

CORROSIONSCIENCEANDPROTECTIONTECHNOLOGY

参比电极体系内阻对电化学阻抗谱的影响

李谋成曾潮流林海潮

(金属腐蚀与防护国家重点实验室中国科学院金属研究所沈阳110016)

摘要在参比电极体系有无鲁金毛细管的条件下,测定了316不锈钢在不同浓度NaCl溶液中的电化学阻抗谱.实

验结果表明参比电极体系内阻和溶液电导率对电化学阻抗谱的高频相移均有较大的影响.

关键词电化学阻抗谱高频相移参比电极体系鲁金毛细管

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中图分类号TG174.36文献标识码A文章编号200103012503

EFFECTOFINTERNALRESISTANCEOFREFREENCEELECTRODESYSTEM

ONELECTROCHEMICALIMPEDANCESPECTROSCOPY(EIS)

LIMoucheng,ZENGChaoliu,LINHaichao

(StateKeyLaboratoryforCorrosionandProtection,

)

InstituteofMetalResearch,TheChineseAcademyofSciences,Shenyang110016

ABSTRACTTheextraneoushigh-frequencyphaseshiftsinEIScanobscureexperimentaldataandcloud

thetrueanalysisofaspectrum.Soitisveryimportanttodiscerntheartifactsresultedfromvariousfactorsdur

ingexperimentandanalysis.TheEISsof316stainlesssteelinNaClsolutionsofdifferentconcentrationswere

measuredwithandwithoutLuggincapillary.Theresultsshowedthatthelargeinternalresistanceoftherefer

enceelectrodesysteminducedcapacitivehigh-frequencyphaseshiftinimpedancemeasurement.Itwasalso

observedthathigh-frequencyphaseshiftswerereducedwiththedecreaseofsolutionres