渭师院高分子物理课件03高分子溶液.pptVIP

共混体系的热力学分析方法Binodalcurve双节线Spinodalcurve旋节线Inflexion拐点MinimumvaluesPhaseequilibriumofsolutionsStable,metastableandnon-stableregions?GMcanbesubstitutedby?1andTemperatureCriticalpoint临界点DeductionBinodalcurvesatisfiesSpinodalcurvesatisfiesTheminimumvalueinthebinodalcurveTheminimumvalueinthespinodalcurveThecoordinateofCpointWherexAandxBarethemeannumbersofsegmentsonAchainandBchain,respectively.DifferentphaseequilibriumdiagramsPhaseseparationanddissolutionarecontrolledbythreevariables:temperature,pressure,andco