渭师院高分子物理课件07聚合物的粘弹性.pptVIP

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  • 2026-04-25 发布于湖北
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渭师院高分子物理课件07聚合物的粘弹性.ppt

TimetemperatureequivalenceprincipleItwasfoundinthe1940‘sthatthemechanicalpropertiesofapolymeratagiventemperaturecouldberelateddirectly(byaconstantshiftfactor位移因子)tothebehavioratanothertemperature.Similarly,thebehavioratagivenratecouldberelateddirectlytoanotherratebyasimilarshiftfactor.RateandtemperatureareinverselyrelatedforthesematerialsbytheTime-TemperatureequivalenceprinciplewhichisbasedontheWilliams-Landel-Ferry(WLF)equationandafreevolumeapproach.Example——Polybutadiene适用范围Tg~Tg+100TgTg+100参考温度T0经验常

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