储氢材料06-Hydrogen Storage materials.PPT

Cycling life of V2.1TiNi0.3, V2.6TiNi0.2 and V3.2TiNi0.16 alloys (charged at 100mA/g, dischaged at 50mA/g) Ⅳ. V-based alloys for electrochemical application 4) V2.1TiNix (x=0.1, 0.3, 0.5, 0.7, 0.9) alloy － R. Guo, L.X. Chen et al. All alloys have a main V-based solid solution phase; The secondary phase is noticeably dispersed along the grain boundaries of the main phase especially with higher nickel contents; As x≥0.5, the secondary phase starts to encompass the main phase completely, forming a three-dimensional network; Ⅳ. V-based alloys for electrochemical application SEM graphs of the V2.1TiNix (x = 0.1~ 0.9) alloys (a) x=0.1; (b) x=0.3; (c) x=0.5; (d) x=0.7; (e) x=0.9 Ⅳ. V-based alloys for electrochemical application V2.1TiNi0.5 alloy with a good combination of the main phase and the secondary phase has the best overall electrochemical performance: Cmax = 392.5 mAh/g at 25mA/g ; 372.4 mAh/g at 50 mA/g ; R30 = 70.60% after 30 cycles. Cycling life for V2.1TiNix alloys (charged at 100 mA/g and discharged at 50 mA/g) Ⅳ. V-based alloys for electrochemical application V2.1TiNi0.3 ? or V2.1TiNi0.5 ? V2.1TiNix (x=0.2, 0.3, 0.4, 0.5, 0.6) alloy － F.B. Dai, L.X. Chen et al. V2.1TiNi0.4 alloy shows the highest discharge capacity: Cmax = 457 mAh/g at 25mA/g; 363 mAh/g at 50 mA/g; R30 = 40.5% after 30 cycles. Ⅳ. V-based alloys for electrochemical application 4.2 Multi-component alloying Ⅳ. V-based alloys for electrochemical application 1) V3TiNi0.56Mx (M= Hf, Zr, Nb, Ta, Al, Si, Mn, Fe, Co etc.; x =0.046, 0.24) All alloys are composed of a main V-based solid solution phase and a secondary phase; The alloys with Zr (x=0.24) or Hf have a C14 Laves secondary phase, the secondary phase of other alloys are still TiNi based phase; Among the alloys studied, the Hf-contained alloys, such as V3TiNi0.56Hf0.046 and V3TiNi0.56Hf0.24, have good discharge capacities and HRD, and poor cycling