储氢材料08-Hydrogen Storage materials.PPTVIP

Tel: 0571- 8795 1152 Email: lxchen@ Laboratory of Hydrogen Storage Materials Institute of Metallic Materials Zhejiang University Hydrogen Storage Materials Dr. Li-xin Chen Kinetics for Hydriding / dehydriding of Hydrogen Storage Alloys Lecture VII 1.1 Experimental procedures 1) Reactor design (1) Purpose: Reducing the effects of heat and keeping constant temperature of reaction system. (2) Methods: I . Kinetics for hydriding/dehydriding of HSAs in gas-solid reaction ①Increasing the contact surface; ②Decreasing the amount of HSA powders; ③Improving the heat transferability. (3) Development of reactor ①Autoclave reactor ( 第一代高压釜式反应器) Features: larger amount of sample powders; 1.1 Experimental procedures small contact surface. HSA ②Thin discal reactor Features: sample powders ↓; 1.1 Experimental procedures heat transferability ↑; thermal flow in only one direction. Temp. controlling system HSA ③Double-wall reactor Features: 1.1 Experimental procedures sample powders ↓↓; heat transferability ↑↑, ΔT 1℃. HSA Temp. controlling system 2) Experimental methods (1) Isochoric method ( 等容法) Features: 1.1 Experimental procedures easily monitoring pressure change; 1.1 Experimental procedures controllability of initial pressure for targeting a given final composition; suitable for studying HSAs with one phase in solid solution region; unsuitable for studying the reaction kinetics with respect to phase transformation. Because hydrogenation process includes solid solution and phase transformation, it is hardly distinguished. (2) Isobaric method ( 等压法) 1.1 Experimental procedures 1.1 Experimental procedures Features: easily for detailed analysis of the experimental data; suitable for studying HSAs with two phases in phase transformation region; unsuitable for studying HSAs with one phase in solid solution region. (3) Isothermal method ( 等温法, on a double-wall reactor) 1.1 Experimental procedures ii) Mixing sample powders with other unreactive metallic powders (such as Ni, Al, Cu